Updated on 2024/06/30

写真a

 
Tsukuda Toshiaki
 
Organization
Graduate Faculty of Interdisciplinary Research Faculty of Education Human Science (Advanced Studies on Transforming Educational Practice) Professor
Title
Professor
Contact information
メールアドレス

Research History

  • Graducate School of Science, Osaka University, Lecturer(Associate Professor)

    2010.4

  • Faculty of Engineering, Seikei University, Research Associate

    2002.4

Education

  • Osaka University

    - 2002.3

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    Country: Japan

  • Okayama University

    - 1999.3

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    Country: Japan

  • Osaka University

    - 1997.3

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    Country: Japan

Degree

  • Doctor of Science (Ph.D.) ( 2002.3   Osaka University )

Research Areas

  • Nanotechnology/Materials / Inorganic/coordination chemistry  / Coordination chemistry Photochemistry

Research Interests

  • high-efficient emitter

  • Luminescent mechanochromism

Subject of research

  • Synthesis of high-efficient luminescent metal complexes

  • Mechanism of photoluminescent mechanochromism for the metal complexes

Papers

  • A Series of Mixed-Ligand Cu(I) Complexes Comprising Diphosphine-Disulfide Ligands: Effects of Diphosphine Ligands on Luminescent Properties Reviewed Major achievement

    INORGANIC CHEMISTRY   59 ( 17 )   12375 - 12384   2020.8( ISSN:0020-1669 )

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.inorgchem.0c01445

  • Crystal structure of [N,N-bis­­(di­phenyl­phospho­ro­thio­yl)amidato-κ2S,S′]bis­­(tri­phenyl­phosphane-κP)copper(I) di­chloro­methane monosolvate Reviewed Major achievement

    Tatsuya Nishi, Toshiaki Tsukuda, Michihiro Nishikawa and Taro Tsubomura

        73 ( 8 )   1105 - 1107   2017.8

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    Language:English   Publishing type:Research paper (scientific journal)  

  • Structures and photophysical properties of copper(I) complexes bearing diphenylphenanthroline and bis(diphenylphosphino)alkane: the effect of phenyl groups on the phenanthroline ligand Reviewed Major achievement

    DALTON TRANSACTIONS   44   7554 - 7562   2015.7( ISSN:1477-9226 )

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)  

  • Counteranion-dependent mechanochromism of a photoluminescent platinum(II) complex with mixed terpyridine and thioglucose Reviewed Major achievement

    CHEMICAL COMMUNICATIONS   50   13529 - 13532   2014.9( ISSN:1359-7345 )

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    Language:English  

  • Highly emissive platinum(II) complexes bearing carbene and cyclometalated ligands Reviewed Major achievement

    DALTON TRANSACTIONS   42 ( 20 )   7396 - 7403   2013.5( ISSN:1477-9226 )

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    Language:English   Publishing type:Research paper (scientific journal)  

  • Sulfur transfer reaction from phosphine sulfides to phosphines assisted by metal ions Reviewed Major achievement

    INORGANICA CHIMICA ACTA   384   149 - 153   2012.4( ISSN:0020-1693 )

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  • Dinuclear macrocyclic palladium complexes having pincer coordinating groups and their catalytic properties in Mizoroki-Heck reactions Reviewed Major achievement

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   696 ( 23 )   3657 - 3661   2011.11( ISSN:0022-328X )

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)  

  • [μ-1,2-bis(diphenylphosphanyl)benzene-κ2P:P']bischrolidgold(I) Reviewed Major achievement

    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE   E67   m121   2011.4( ISSN:1600-5368 )

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)  

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Books and Other Publications

  • 錯体化合物事典

    ( Role: Contributor化合物6点について執筆)

    朝倉書店  2019.9   ISBN:978-4-254-14105-4

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    Total pages:6   Language:Japanese   Book type:Dictionary, encyclopedia

  • 演習で学ぶ無機化学 基礎の基礎

    秋津貴城、佃俊明( Role: Joint Translation )

    化学同人  2019.3   ISBN:9784759819809

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    Total pages:180   Language:Japanese   Book type:Textbook, survey, introduction

    無機化学の初学者向けの演習書.トピックごとに,概要,例題と解説,さらに練習問題を掲載.例題は典型的な問題がほとんどで,問題の解き方だけでなく,よくある間違えも掲載されている.数式なども丁寧に解説されていて,院試対策に最初に取り組むべきテキスト.演習講義の教科書,試験対策として自学習用にもオススメ.

  • 好きになる化学基礎実験

    丸田銓二朗・山根兵・丸田俊久・佃 俊明( Role: Joint Work新しく導入した実験部分(4.6、補遺など)と陽イオン分析を中心とした改訂部分)

    三共出版  2017.3   ISBN:978-4-7827-0757-9

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    Responsible for pages:86~87, 92,   Language:Japanese   Book type:Textbook, survey, introduction

    見やすく,わかりやすい実験書をスローガンとして,全体の実験操作をフローチャートで示して,実験の全体の流れが視覚的に把握できるようにした。さらに,各操作段階での要点を簡潔に解説したので,実験中に手順や操作の確認にも,すぐ参照できるよう対応した。

  • Basic Inorganic Chemistry

    Taro Tsubomura, Tatsuya Kawamoto, Toshiaki Tsukuda( Role: Joint Work)

    Kagaku-Dojin Publishing Company,INC  2017.2   ISBN:9784759818376

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    Total pages:74   Responsible for pages:1~74   Language:Japanese   Book type:Textbook, survey, introduction

Presentations

  • Luminescent Mechanochromic Behaviors of Dinuclear Silver(I) Complexes Bridged by Various Anionic Ligands Invited International conference Major achievement

    43rd International Conference on Coordination Chemistry  2018.7 

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    Event date: 2018.7

    Language:English   Presentation type:Oral presentation(general)  

    Venue:Sendai International Center, Sendai, Miyagi  

    We also found that dinuclear complexes bridged by halogenide ions, [Ag2(m-X)2(dppbz)2] (X = Cl, Br, I) shows luminescent mechanochromism. These complexes shows blue or greenish-blue emission (X = Cl, 490 nm; X = Br, 471 nm;
    X = I, 474 nm). On grinding, emission color of the complexes turns green (lmax = 538 nm). On heating at 180 ºC, the maximum of emission wavelength became ca. 500 nm. Our study also reveals that dinuclear Ag(I) complexes bridged by phenythiolato ions, [Ag2(m-RPhS)2(dppbz)2] (R = Me, Cl) and mononuclear complexes with other diphosphines bridged by an aromatic ring like dppbz also show such mechanochromic behavior.

  • Luminescent Mechanochromism of Dinuclear Cu(I) Complexes Bridged by Toluene-thiolato Groups Major achievement

    Toshiaki Tsukuda, Saori Shimura, Daiki Harada, Yasuhito Takei

    The 68th Conference of Japan Society of Coordination Chemistry  2018.7  Japan Society of Coordination Chemistry

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    Event date: 2018.7

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Sendai International Center, Sendai, Miyagi  

    Treatment of o- or m- toluenethiolate with Cu2O and dppbz (1,2-(diphneylphosphino)benzene) gave the corresponding emissive dinuclear Cu complexes. Both of complexes showed mechanochromic behavior: on grinding, emission maxima was shifted to lower energy. On heating of the ground samples, they showed higher energy emission than that of ground samples.

  • Luminescent properties of dinuclear silver(I) complexes bridged by toluene thiolato groups Invited

    Toshiaki Tsukuda, Saori Shimura, Shiho Imamura

    The 67th conference of JSCC  2017.9 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Poster presentation  

  • Luminescent mechanochromism of dinuclear copper(I) compelxes with disphosphines and bridging thiolato ligands

    Toshiaki Tsukuda, Yasuhito Takei, Daiki Harada

    2017.8 

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    Event date: 2017.8

    Language:Japanese   Presentation type:Poster presentation  

  • Luminescent Mechanochromic System of Ag(I) Complexes Containing Diphosphine Ligands International conference Major achievement

    The 23rd International SPACC Symposium  2016.11 

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    Event date: 2016.11

    Language:English   Presentation type:Oral presentation(general)  

  • Structure and Luminescent Properties of Dinuclear Cu(I)-diphosphine Complexes Bridged by Thiophenolate Groups

    Toshiaki TSUKUDA, Yasuhito TAKEI, Daiki HARADA

    Japan Society of Coordination Chemistry, 66th Symposium  2016.9 

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Fukuoka University  

  • Luminescent Mechanochromic Behaviors of d10 Metal Complexes with Diphosphine Ligand Bridged by an Aromatic Group

    3rd International Symposium on the Photofunctional Chemistry of Complex Systems  2015.12 

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    Event date: 2015.12

    Language:English   Presentation type:Oral presentation(invited, special)  

  • Luminescent mechanichromism of Ag(I) complexes bridged by anionic ligands

    2015.8 

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    Event date: 2015.8

    Language:Japanese   Presentation type:Oral presentation(general)  

  • Mechanism of luminescent mechanochromism for the metal complexes coordinated by 1,2-bis(diphenylphosphino)benzene Major achievement

    2013.11 

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    Event date: 2013.11

    Language:Japanese   Presentation type:Oral presentation(general)  

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The total number of announcement other than the above

  • 2016

    Total number of non-preannounced events:2  Number of main presenters:2  Number of presenters other than main person:0

Teaching Experience (On-campus)

  • Essence and Ggoals / Content Structure of Science Major achievement

    2023Year

  • Chemistry Seminar I Major achievement

    2023Year

  • General Chemistry Major achievement

    2023Year

  • Experiments for Elementary School Teachers

    2023Year

Teaching achievements

  • 第4回教育学域FD研修会「山梨県における教科担任制の現状と課題」

    2022.01.25

Social Activities

  • 山梨県スーパーサイエンスハイスクール高大連携事業

    Role(s): Lecturer

    山梨大学M号館209号室  2019.8

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    Audience: High school students

    Type:Visiting lecture

    「ブラックライトを当てると光る金属錯体を作ろう」という題目で、発光性錯体の合成を行った。 

  • 山梨県スーパーサイエンスハイスクール高大連携事業

    Role(s): Lecturer

    山梨大学M号館209号室  2018.8

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    Audience: High school students

    Type:Visiting lecture

    「ブラックライトを当てると光る金属錯体を作ろう」という題目で、発光性錯体の合成を行った。 

Professional Memberships

  • The American Chemical Society

    2013.4

  • The Photofunctional Complexes Research Association, Japan

    2010.4

  • Japan Society of Coordination Chemistry

    2001.5

  • The Chemical Society of Japan

    2000.11