Organization
Graduate Faculty of Interdisciplinary Research Faculty of Engineering Materials Science (Clean Energy Research Center) Professor
Title
Professor
Contact information
Miyao Toshihiro
Research History
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University of Yamanashi, Fuel Cell Nanomaterials Center
2008.4
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University of Yamanashi
2008.4
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Kanagawa University Kanagawa University
1998.3
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Kanagawa University
1998.3
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Nissan Chemical Industry
1996.4
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日産化学工業株式会社
1996.4
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Asahi Glass Company
1991.4
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旭硝子株式会社
1991.4
Education
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Tokyo University of Agriculture and Technology
1993.4 - 1996.3
Country： Japan
Course： Doctor later
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Tokyo University of Agriculture and Technology
1989.4 - 1991.3
Country： Japan
Course： Doctor prophase
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Tokyo University of Agriculture and Technology
1985.4 - 1989.3
Country： Japan
Course： Others
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Tokyo Metropolitan Mitaka High School
- 1984.3
Country： Japan
Degree
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Ph.D. ( 1996.3 Tokyo University of Agriculture and Technology )
Research Areas
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Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Catalyst and resource chemical process Major achievement
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Nanotechnology/Materials / Inorganic materials and properties Major achievement
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Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Chemical reaction and process system engineering Major achievement
Research Interests
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insitu measurements
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hydrogen production and purification
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Reversed water system for the preparation of nano particles of metal and metal oxide
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catalyst deactivation
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meso- and microporous materials
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物理化学
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水素製造精製
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機能材料・デバイス
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反応工学・プロセスシステム
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その場観察法
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規則的メソ多孔体
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高活性高耐久性
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逆ミセル法
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触媒・資源化学プロセス
Subject of research
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燃料電池自動車用電極触媒の開発
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COおよびCO2水素化触媒の開発と反応機構の解析
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Development of highly active catalyst for hydrogen production and purification, hydrogen production by NH3 decomposition, in situ measurements by various spectroscopic techniques
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高次多孔体材料の開発とその吸着特性の解析
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種々の分光法を用いた固体表面の構造と触媒作用の解明
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担持金属触媒の吸着特性と触媒作用の解明
Proposed theme of joint or funded research
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固体触媒を用いた種々の化学反応プロセスの開発・改良
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多孔質材料を用いた吸着および環境浄化プロセスの開発
Research Projects
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高効率・高出力・高耐久PEFCを実現する革新的材料の研究 (ECCEED30-FC PJ) Major achievement
2024.4 - 2025.3
新エネルギー・産業技術総合開発機構（NEDO） NEDO委託事業
Grant type：Competitive Type of fund：：Others
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高出力･高耐久･高効率燃料電池材料のコンセプト創出(Sper-FC PJ) Major achievement
2016.4 - 2020.2
新エネルギー・産業技術総合開発機構（NEDO） NEDO委託事業 定置用燃料電池システムの低コスト化のためのMEA高性能化、高耐久性CO選択メタン化触媒の開発
Grant type：Competitive Type of fund：：Others
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定置用燃料電池システムの低コスト化のためのMEA高性能化、高耐久性CO選択メタン化触媒の開発 Major achievement
2013.4 - 2015.3
新エネルギー・産業技術総合開発機構（NEDO） NEDO委託事業
Authorship：Coinvestigator(s) Grant type：Competitive Type of fund：：Others
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燃料電池の性能評価方法等に関する国際標準化 Major achievement
2018.4 - 2021.3
経産省 経産省委託事業
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水素を選択的に活性化し低温でアンモニアを生成するナノ反応場分離触媒の研究 Major achievement
2018.4 - 2021.3
基盤研究C
Authorship：Principal investigator Grant type：Competitive Type of fund：：Science research expense
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劣化機構解析とナノテクノロジーを融合した高性能セルのための基礎的材料研究(Hiper-FC PJ) Major achievement
2008.4 - 2015.3
新エネルギー・産業技術総合開発機構（NEDO） NEDO委託事業
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熱暴走抑制機能を有する新規な複合酸化物担持金属触媒の開発 Major achievement
2012.4 - 2015.3
基盤研究C
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燃料電池ナノ材料研究拠点の整備 Major achievement
2010.7 - 2014.3
文部科学省 文科省低炭素社会構築に向けた研究基盤ネットワークの整備事業
Grant type：Competitive Type of fund：：Others
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新規な高純度水素製造プロセス開発を目的としたメタノールの液相改質反応
2006.4 - 2009.3
基盤研究C
Grant type：Competitive Type of fund：：Science research expense
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金属－酸化物ナノ構造体の壁構造の制御と新しい触媒調製法の開発
2006.4 - 2009.3
基盤研究B
Grant type：Competitive Type of fund：：Science research expense
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規則的なナノ構造を有する高表面積半導体酸化物触媒の開発と水の光分解
2002.4 - 2005.3
基盤研究B
Grant type：Competitive Type of fund：：Science research expense
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逆ミセル中の超微小空間における水の高効率光分解の研究
1999.4 - 2002.3
奨励研究A
Grant type：Competitive Type of fund：：Science research expense
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カーボンリサイクル・次世代火力発電等技術開発／CO2排出削減・有効利用実用化技術開発／ 液体燃料へのCO2利用技術開発
2025.4 - 2028.3
国立研究開発法人新エネルギー・産業技術総合開発機構（NEDO） NEDO交付金事業
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メタノールの液相改質反応の研究
2005
Grant type：Competitive
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金属クラスターを内包した酸化物ナノ構造体の合成とその触媒特性の研究
2005
Grant type：Competitive
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遷移金属炭化物触媒を用いたメタンの改質反応の研究
Grant type：Competitive
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逆ミセル法による酸化物微粒子の調製
Grant type：Competitive
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水素製造精製プロセスのための新規な高活性高耐久性触媒の開発
Grant type：Competitive
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W/Oエマルションを反応場とする水の光環元の研究
Grant type：Competitive
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Study of photo-assisted water reduction in W/O emulsion
Grant type：Competitive
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Study of methane reforming over transition metal carbide catalysts
Grant type：Competitive
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Preparation of metal oxide fine particles by revesed micelle
Grant type：Competitive
Papers
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Application of in situ TEM observation in the development of electrocatalysts for PEFCs: Pt/ordered mesoporous carbon with network structure Reviewed Major achievement
Hanako Nishino, Satoko Sato, Hiroko Yamazaki, Takeo Kamino, Makoto Uchida, Akihiro Iiyama, Toshihiro Miyao
Chemistry Letters 54 2025.3( ISSN：1348-0715 )
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Pyrolyzed Iron-Cobalt/Polypyrrole/reduced Graphene Oxide as an Effective Cathode Electrocatalyst for Oxygen Reduction Reaction in an Alkaline Medium Reviewed International coauthorship Major achievement
H. Necesito, J. Garcia, E. Dzmarado, T. Miyao, J. Inukai, B. Tongol
Journal of Physics and Chemistry of Solids 199 112556 - 112570 2025.1( ISSN：1879-2553 )
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Graphitic carbon nitride on reduced graphene oxide prepared via semi-closed pyrolysis as electrocatalyst for oxygen reduction reaction Reviewed International coauthorship Major achievement
J. Garcia, T. Miyao, J. Inukai, B. Tongol
Materials Chemistry and Physics 288 126415 - 126424 2022.6( ISSN：1879-3312 )
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The Possibility of Intermediate–Temperature (120 oC)–Operated Polymer Electrolyte Fuel Cells (IT–PEFCs) using Perfluorosulfonic Acid Polymer Membranes Reviewed Major achievement
K. Kakinuma, H. Taniguch, T. Asakawa, T. Miyao, M. Uchida, Y. Aoki, T. Akiyama, A. Masuda, N. Sato, A. Iiyama
Journal of The Electrochemical Society 169 44522 - 44531 2022.3( ISSN：1945-7111 )
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Catalytic activity and durability of a mesoporous silica-coated Ni-alumina-based catalyst for selective CO methanation Reviewed Major achievement
Catalysis Today 2014.11
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Preparation and Catalytic Activity of a Mesoporous Silica-Coated Ni-Alumina-Based Catalyst for Selective CO Methanation Reviewed Major achievement
Catalysis Communications 58 93 - 96 2014.10
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Mechanistic Study of the Effect of Chlorine on Selective CO Methanation over Ni Alumina-Based Catalysts Reviewed Major achievement
Applied Catalysis A General 486 187 - 192 2014.9
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High catalytic performance of mesoporous zirconia supported nickel catalysts for Selective CO Methanation Reviewed Major achievement
Catalysis Science & Technology 4 2508 - 2511 2014.4
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Correlation between surface chemical composition with catalytic activity and selectivity of organic-solvent synthesized Pt-Ti Reviewed Major achievement
Journal of Materials Chemistry A 1 8798 - 8804 2013.6
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Mechanistic Study of Hydrogen Occlusion in Hollow Silica Nano-spheres Encapsulating Iridium Metal Reviewed Major achievement
Journal of Molecular Catalysis A: Chemical 378 174 - 178 2013.6
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Preparation of graphite supported Li-N-H hydrogen storage material from Li-graphite intercalation compound and their unique hydrogen release property Reviewed Major achievement
International Journal of Hydrogen Energy 36 6751 - 6755 2011.6
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High Temperature Water-Gas Shift Reaction over Hollow Ni-Fe-Al Oxide Nano-Composite Catalysts Prepared by the Solution-Spray Plasma Technique Reviewed Major achievement
Catalysis Communications 10 1952 - 1955 2011.4
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Preparation of a mesoporous ceria–zirconia supported Ni–Fe catalyst for the high temperature water–gas shift reaction Reviewed Major achievement
Catalysis Communications 12 976 - 979 2011.4
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H2O-Tolerant Monolithic Catalysts for Preferential Oxidation of CarbonMonoxide in the Presence of Hydrogen Reviewed Major achievement
Appl. Catalysis A: General 370 50 - 53 2011.4
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Compact fuel processor by employing a monolithic catalyst for 1 kW class residential polymer electrolyte fuel cells Reviewed Major achievement
J. Jpn. Petrol. Inst. 54 52 - 55 2011.1
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Metal-Monolithic Catalysts for Selective CO Methanation Reviewed Major achievement
J. Jpn. Petrol. Inst. 2010.12
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High Catalytic Performance of Ru-Doped Mesoporous Ni-Al Oxides for Selective CO Methanation Reviewed Major achievement
Angewandte Chemie International Edition 2010.11
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Ni-Fe-Ce Mixed Nano-composite Oxide Catalyst Prepared by Solution-spray Plasma Technique for High Temperature Water-gas-shift Reaction Reviewed Major achievement
J. Jpn. Petrol. Inst. 53 ( 6 ) 367 - 368 2010.11
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Effect of Re and Mo addition upon liquid phase methanol reforming with water over SiO2, ZrO2 and TiO2 supported Ir catalysts Reviewed Major achievement
International J. Hydrogen Energy 35 ( 12 ) 6203 - 6209 2010.3
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Selective methanation of CO in hydrogen-rich gases involving large amounts of CO2 over Ru-modified Ni-Al mixed oxide catalyst Reviewed Major achievement
Applied Catalysis A General 370 ( 1-2 ) 182 - 187 2010.3
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Promoting effect of MgO addition to Pt/Ni/CeO2/Al2O3 in the steam gasification of biomass Reviewed Major achievement
Applied Catalysis B Environmental 86 36 - 44 2009.2
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Oxidative steam reforming of methane over Ni/alpha-Al2O3 modified with trace Pd Reviewed Major achievement
Applied Catalysis A General 351 217 - 225 2008.12
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Marked capability for hydrogen occlusion of hollow silica nanospheres containing group 8-10 metal clusters Reviewed Major achievement
Catalysis Today 132 132 - 137 2008.3
Presentations
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ネットワーク構造を有する規則メソポーラスカーボン担持白金触媒の構造とORR特性 Major achievement
宮尾敏広，西野華子，山崎博子，佐藤智子，田本加代子， 斉藤圭亮，小泉直人，干川康人，内田誠，飯山明裕
電気化学会第92回大会 2025.3 電気化学会
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山梨大学におけるグリーン水素研究： 国内・国際連携で拓く新たなステージ Invited Major achievement
宮尾敏広
福島県内大学連携水素・カーボンニュートラルオープンセミナー 2025.3 福島大学
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Morphology Changes of Pt Supported on an Ordered Mesoporous Carbon with Network-Structure: in situ TEM Observation of a PEFC Electrocatalyst International conference Major achievement
Hanako Nishino, Satoko Sato, Hiroko Yamazaki, Takeo Kamino, Makoto Uchida, Akihiro Iiyama, Naoto Koizumi, Toshihiro Miyao
PRiME2024 2024.10 The Electrochemical Society
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The Formation Mechanism of Ordered Mesoporous Carbon with Network-Structure: A Novel Support Material for Pt-Based Catalysts in PEFC Cathodes International conference Major achievement
Toshihiro MIYAO, Hanako Nishino, Hiroko Yamazaki, Satoko Sato, Kayoko Tamoto, Makoto Uchida, Akihiro Iiyama, Kazuya Shibanuma, Mika Sodeno, Naoto Koizumi, Yasuto Hoshikawa
244th ECS Meeting 2023.10 The Electrochemical Society
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Development of Highly Active Pt/C-Based Catalysts for the ORR Using an Ordered Mesoporous Carbon with Network Structure as a Support Material: Focus on the Pt Loading Process International conference Major achievement
Satoko Sato, H. Yamazaki, H. Nishino, K. Tamoto, M. Uchida, A. Iiyama, K. Shibanuma, M. Sodeno, N. Koizumi, Y. Hoshikawa, T. Miyao
244th ECS Meeting 2023.10 The Electrochemical Society
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Development of Pt/C-based Cathode Catalysts for PEFCs through a Novel Concept: Synthesis of Ordered Mesoporous Carbon Support with Hierarchical Network-Like Structure Invited International conference Major achievement
Toshihiro Miyao
2023UST-UY Joint Symposium 2023.7 Saint Thomas University
Industrial Property Rights
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担持金属触媒及びその製造方法、担体の製造方法 Major achievement
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一酸化炭素の選択的メタン化触媒、その製造方法及びそれを用いた装置 Major achievement
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燃料改質装置、一酸化炭素の選択的メタン化方法、一酸化炭素の選択的メタン化触媒及びその製造方法 Major achievement
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CO選択メタン化触媒 Major achievement
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一酸化炭素メタン化触媒組成物及び一酸化炭素メタン化触媒 Major achievement
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ＣＯ選択メタン化反応器 Major achievement
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CO選択メタン化触媒 Major achievement
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アンモニア分解触媒とその製造方法および、これを用いた装置 Major achievement
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燃料電池用電極触媒及びその製造方法 Major achievement
-
担持金属触媒及びその製造方法、担体の製造方法 Major achievement
-
担持金属触媒及びその製造方法 Major achievement
-
燃料電池電極触媒材料 Major achievement
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燃料電池電極触媒材料 Major achievement
-
燃料電池電極触媒材料 Major achievement
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燃料電池電極触媒材料 Major achievement
Teaching Experience (On-campus)
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Fundamentals of Inorganic Chemistry Major achievement
2024Year
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Advanced Course of Science for Surfaces and Interfaces Major achievement
2024Year Type of subject：Master's (Graduate School)
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Advanced Multidiscipline Engineering
2023Year
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Advanced Course of Science for Surfaces and Interfaces
2023Year
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Advanced Analytical Chemistry
2023Year
Social Activities
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2012.4
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2009.4 - 2011.3
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2008.4 - 2009.3
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2006.4 - 2008.3
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2004.4 - 2008.3
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2004.4 - 2008.3
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2001.4 - 2004.3
Professional Memberships
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American Chemical Society
2014.3
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The Japan Petroleum Institute
2000
-
Catalysis Society of Japan
1989
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The Chemical Society of Japan
1989
Committee Memberships
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触媒学会 工業触媒研究会世話人
2024.4
Committee type：Society
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触媒学会 燃料電池研究会世話人
2019.4
Committee type：Society
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触媒学会 触媒学会ナノ粒子研究会世話人
2008.9
Committee type：Society
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触媒学会関東地区幹事 その他の委員、役員
2008.9
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触媒学会代議員 その他の委員、役員
2008.9
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触媒学会触媒誌編集委員 その他の委員、役員
2008.9 - 2010.3
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石油学会ペテロテック誌編集委員
2008.9
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触媒学会関東地区幹事
2008.9
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触媒学会関東地区事業委員
2008.9
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触媒学会触媒誌編集委員
2008.9
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触媒学会代議員
2008.9
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触媒学会ナノ粒子研究会幹事
2008.9
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触媒学会関東地区事業委員 その他の委員、役員
2006.9 - 2009.3
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石油学会ペテロテック誌編集委員 その他の委員、役員
2006.4 - 2008.3